1-(6-Ferrocenylhexyl)-1H-imidazole

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1-(6-Ferrocenylhex­yl)-1H-imidazole

The title compound, [Fe(C(5)H(5))(C(14)H(19)N(2))], is characterized by a ferrocenyl group separated from an imidazole functionality by a straight-chain hexyl unit. The two cyclo-penta-dienyl rings of the ferrocenyl group show a marginal inward tilt of 2.17 (2)°. The imidazole unit, which is essentially planar (with a maximum deviation of 0.007 A for one of the N atoms) and tilted away from the...

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1-Ferrocenylmeth­yl-1H-imidazole

In the title compound, [Fe(C(5)H(5))(C(9)H(9)N(2))], the distances of the Fe atom from the centroids of the unsubstituted and the substituted cyclo-penta-dienyl (cp) rings are 1.639 (1) and 1.647 (1) Å, respectively. The ferrocenyl unit deviates from an eclipsed geometry with tilted cp rings; the inter-planar angle between the cp and imidazole rings is 114.11 (4)°.

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4-Phenyl-1H-imidazole (a low-temperature redetermination), 1-benzyl-1H-imidazole and 1-mesityl-1H-imidazole.

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4-Hydroxy­benzoic acid–1H-imidazole (1/1)

In the title 1:1 adduct, C(7)H(6)O(3)·C(3)H(4)N(2), the crystal packing features π-π stacking inter-actions [centroid-centroid distances = 3.799 (2) and 3.753 (1) Å] as well as N-H⋯(O,O) O-H⋯O and C-H⋯O hydrogen bonds.

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In the title compound, C(4)H(5)N(3)O(2), the nitro group is twisted with respect to the imidazole ring by a dihedral angle of 5.60 (2)°. Weak inter-molecular C-H⋯O and C-H⋯N hydrogen bonding is present in the crystal structure.

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ژورنال

عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online

سال: 2010

ISSN: 1600-5368

DOI: 10.1107/s1600536810007737